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![The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
Crystal structure of the lead-containing organic-inorganic hybrid: (C18H26N2)3[Pb4I14(DMSO)2]·2DMSO
1State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong Province, People's Republic of China.
Abstract:
The title compound, tris-(1,1'-dibutyl-4,4'-bi-pyridine-1,1'-diium) bis-(dimethyl sulfoxide)di-μ3-iodido-tetra-μ2-iodido-octa-iodido-tetra-lead(II) dimethyl sulfoxide di-solvate, (C18H26N2)3[Pb4I14(C2H6OS)2]·2C2H6OS, belongs to a class of organic-inorganic hybrid materials with novel functionalities. In this compound, C-H⋯O and C-H⋯I hydrogen-bonding inter-actions, π-π inter-actions, other short contacts and Pb octa-hedral chains are present, extending the crystal structure into a three-dimensional supra-molecular network.
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