Magnetic iron oxide nanoparticles decorated graphene for chemoresistive gas sensing: The particle size effects

We report a synthesis of magnetic nanoparticles chemically immobilized onto reduced graphene oxide sheets (referred to as rGO-Fe₃O₄ NPs) as a gas and vapor sensing platform with precisely designed particle size of 5, 10 and 20 nm to explore their influence of particle size on sensing performance. The rGO-Fe₃O₄ NP sensors have been investigated their responses to different gases and volatile organic compounds (VOCs) at part-per-million (ppm) levels. Results show that the Fe₃O₄ NPs with smaller size (5 and 10 nm) on the rGO surface led to a lower sensitivity, while particles of a size of 20 nm have a significant enhancement of sensitivity compared to the bare rGO sensor. The rGO-Fe₃O₄ NP20 sensor can detect trace amounts of NO₂ gas and ethanol vapor at the 1 ppm and is highly selective to the NO₂ and ethanol among other tested gases and VOCs, respectively. The particle size causes different distribution behaviour of NPs over rGO surface and interspaced between them, which results in deceased or increased the surface interactions between gas and graphene. The NPs themselves contained different defects level and the charge depletion layer that affect their adsorption gas/vapor molecules, which are explained for different sensing responses.