Photovoltage-triggered electrochromic tablet for visualized photoelectrochemical sensing

In this work, we designed an integrated photoelectrochemical (PEC) analytical system with photovoltage-regulated electrochromic tablet for visualized sensing. The electrochromic tablet consisted of electron-injector (EI) part and colorimetric system, which was functionalized with dye-sensitized titanium dioxide and nickel oxide nanosheet film as the recognition element and signal readout, respectively. Under irradiation of home-built white light, the EI part provided sufficient and stable photovoltage and injected the photoexcited electrons to nickel oxide nanosheet through the conductive inner side of indium tin oxide slide. Thus, the different color states of nickel oxide nanosheet were observed, resulting in a detectable signal by naked eyes for visual analysis. More importantly, the color change was identified to be dependent on the photovoltages generated from EI part. Using copper ions as a model analyte, the electrochromic tablet was successfully applied to visually detect copper ions based on its quenching effect on photovoltage due to the formation of exciton trapping. As a result, the copper ions could be simultaneously determined over a wide range through photovoltage record, average RGB value, and naked eyes. Furthermore, the device exhibited considerable stability and could be reused through simple washing steps. The smart tablet PEC system provides a new avenue to design practical PEC sensor in point-of-care diagnosis.