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Nomenclature of Carboxylic Acid Derivatives: Amides and Nitriles01:11

Nomenclature of Carboxylic Acid Derivatives: Amides and Nitriles

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Naming Amides
The IUPAC and common names of amides are derived from the parent carboxylic acid, by replacing the suffix “oic acid” and “ic acid,” respectively, with “amide.” In the following example, the IUPAC name ethanamide is derived from ethanoic acid, and the common name, acetamide, is obtained from acetic acid.
5.4K
Ethers from Alcohols: Alcohol Dehydration and Williamson Ether Synthesis02:29

Ethers from Alcohols: Alcohol Dehydration and Williamson Ether Synthesis

12.9K
Overview
Ethers can be prepared from organic compounds by various methods. Some of them are discussed below,
Preparation of Ethers by Alcohol Dehydration
In this method, in the presence of protic acids, alcohol dehydrates to produce alkenes and ethers under different conditions. For example, in the presence of sulphuric acid, dehydration of ethanol at 413 K yields ethoxyethane, whereas it yields ethene at 443 K.
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Preparation of Amides01:29

Preparation of Amides

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Amides are synthesized by treating carboxylic acids with amines in the presence of dehydrating agents like dicyclohexylcarbodiimide (DCC).
The DCC-promoted synthesis of amides begins with the protonation of DCC by carboxylic acid. The protonation makes it a better acceptor. Next, the addition of carboxylate to the protonated carbodiimide gives a reactive acylating agent.
Subsequently, the amine acts as a nucleophile that attacks the acylating agent to form a tetrahedral intermediate. In the...
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Crown Ethers02:36

Crown Ethers

6.1K
Crown ethers are cyclic polyethers that contain multiple oxygen atoms, usually arranged in a regular pattern. The first crown ether was synthesized by Charles Pederson while working at DuPont in 1967. For this work, Pedersen was co-awarded the 1987 Nobel Prize in Chemistry. Crown ethers are named using the formula x-crown-y, where x is the total number of atoms in the ring and y is the number of ether oxygen atoms. The term 'crown' refers to the crown-like shape that these ether molecules...
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Structure and Nomenclature of Ethers02:28

Structure and Nomenclature of Ethers

14.7K
Structure and Bonding
Ethers are organic compounds with an ether functional group which is characterized by an oxygen atom connected to two — identical or different — alkyl, aryl, or vinyl groups. The C–O–C linkage in dimethyl ether — the simplest ether — has an approximately tetrahedral bond angle of 110.3 degrees. The oxygen atom is sp3- hybridized, with the C–O distance being about 140 pm.
Classification of Ethers
Based on their attached substituent...
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Physical Properties of Ethers02:17

Physical Properties of Ethers

8.5K
Overview
An ether molecule has a net dipole moment due to the polarity of C–O bonds. Subsequently, boiling points of ethers are lower than those of alcohols of comparable molecular weight and slightly higher than those of hydrocarbons of comparable molecular weight (Table 1).
Ethers can act as hydrogen bond acceptors, making them more water-soluble than hydrocarbons, but since ethers cannot act as hydrogen bond donors, they are much less soluble in water than alcohols. Ethers are considered...
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Related Experiment Video

Updated: Jan 30, 2026

Tuning the Acidity of Pt/ CNTs Catalysts for Hydrodeoxygenation of Diphenyl Ether
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Tuning the Acidity of Pt/ CNTs Catalysts for Hydrodeoxygenation of Diphenyl Ether

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Biomass-Derived Poly(ether-amide)s Incorporating Hydroxycinnamates.

Brianna M Upton1, Andrea M Kasko2

  • 1Department of Chemistry and Biochemistry , University of California, Los Angeles , Los Angeles , California 90095 , United States.

Biomacromolecules
|January 24, 2019
PubMed
Summary
This summary is machine-generated.

Researchers developed new lignin-based poly(ether-amide)s from renewable biomass. These high-performance polymers show excellent hydrolysis resistance and tunable properties for sustainable material applications.

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Area of Science:

  • Polymer Chemistry
  • Sustainable Materials Science
  • Biomass Valorization

Background:

  • Lignin is an abundant, low-cost, non-petroleum source of aromatic compounds.
  • Aromatic moieties are crucial for high-performance polymer development.
  • Developing sustainable polymer feedstocks is a key research area.

Purpose of the Study:

  • To synthesize and characterize novel poly(ether-amide)s using lignin-derived hydroxycinnamates.
  • To explore the structure-property relationships of these new polymers.
  • To assess the potential of lignin as a feedstock for advanced polymeric materials.

Main Methods:

  • Incorporation of three lignin-derived hydroxycinnamates (coumaric, ferulic, sinapinic acids) into dimers.
  • Copolymerization of these dimers with seven different aliphatic and aromatic diamines via interfacial polymerization.
  • Characterization of the resulting 21 poly(ether-amide)s, including solubility, thermal properties (Tg, Td), and hydrolysis resistance.

Main Results:

  • A series of 21 novel poly(ether-amide)s were successfully synthesized.
  • The polymers displayed limited solubility in common organic solvents but good solubility in DMF.
  • Moderate glass transition temperatures and thermal stabilities were observed.
  • Excellent resistance to hydrolysis was a key characteristic of the synthesized polymers.

Conclusions:

  • The modular synthetic strategy allows for the creation of diverse polymers with tunable properties.
  • Lignin-derived monomers offer a sustainable route to aromatic polymers.
  • These poly(ether-amide)s show promise for applications requiring high hydrolysis resistance and tailored performance.