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Updated: Jan 30, 2026

Fabricating Reactive Surfaces with Brush-like and Crosslinked Films of Azlactone-Functionalized Block Co-Polymers
Published on: June 30, 2018
Chemically fueled covalent crosslinking of polymer materials
Borui Zhang1, Isuru M Jayalath, Jun Ke
1Department of Chemistry and Biochemistry, Miami University, 651 E High St, Oxford, OH 45056, USA. scott.hartley@miamiOH.edu d.konkolewicz@miamiOH.edu.
Abstract:
Transiently crosslinked dynamic polymer networks are developed, using carbodiimide hydration to link carboxylic acids as anhydrides. From aqueous polymer solutions, non-equilibrium hydrogels are transiently formed, which dissolve upon anhydride hydrolysis. The materials can be refueled using a subsequent injection of carbodiimide. The gels exhibit higher storage moduli compared to transient supramolecular gels as a result of their covalent crosslinks.
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