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Dual-cubic-cage based lanthanide sulfate-carboxylpyrazolate frameworks with high hydrolytic stability and remarkable
Liang He1, Jayanta Kumar Nath, Er-Xia Chen
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China. linqipu@fjirsm.ac.cn.
Abstract:
We report herein a series of lanthanide sulfate-carboxylpyrazolate frameworks based on double cuboid cavities that are highly hot-water stable, and have room-temperature proton conductivity of over 10-3 S cm-1 at 97% relative humidity without any appreciable loss of performance for at least three recycling times, ranking among the best lanthanide-based coordination frameworks.
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