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Covalent Diamond-Graphite Bonding: Mechanism of Catalytic Transformation
Semir Tulić1, Thomas Waitz1, Mária Čaplovičová2
1Physics of Nanostructured Materials, Faculty of Physics , University of Vienna , Boltzmanngasse 5 , 1090 Vienna , Austria.
Abstract:
Aberration-corrected transmission electron microscopy of the atomic structure of diamond-graphite interface after Ni-induced catalytic transformation reveals graphitic planes bound covalently to the diamond in the upright orientation. The covalent attachment, together with a significant volume expansion of graphite transformed from diamond, gives rise to uniaxial stress that is released through plastic deformation. We propose a comprehensive model explaining the Ni-mediated transformation of diamond to graphite and covalent bonding at the interface as well as the mechanism of relaxation of uniaxial stress. We also explain the mechanism of electrical transport through the graphitized surface of diamond. The result may thus provide a foundation for the catalytically driven formation of graphene-diamond nanodevices.
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