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Updated: Jan 27, 2026

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Applying X-ray Imaging Crystal Spectroscopy for Use as a High Temperature Plasma Diagnostic
Published on: August 25, 2016
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Schrödinger Correspondence Applied to Crystals.
Eric J Heller1,2, Donghwan Kim1
1Department of Chemistry and Chemical Biology , Harvard University , Cambridge , Massachusetts 02138 , United States.
The Journal of Physical Chemistry. A
|March 21, 2019
Summary
Schrödinger
Area of Science:
- Condensed Matter Physics
- Quantum Mechanics
- Solid State Physics
Background:
- The Schrödinger Correspondence Principle (1926) links quantum and classical mechanics for harmonic oscillators.
- Extending this principle to N-dimensional systems offers a classical approach to quantum problems in harmonic solids.
- Understanding phonons, pseudomomentum, and center-of-mass momentum is crucial for applying this principle.
Purpose of the Study:
- To clarify concepts like phonons and pseudomomentum for applying the correspondence principle.
- To introduce the concept of the antiphonon in atomic systems.
- To analyze quantum behavior in harmonic solids using classical methods via the correspondence principle.
Main Methods:
- Extension of the Schrödinger Correspondence Principle to N-dimensional harmonic oscillators.
- Conceptual clarification of phonons, pseudomomentum, and center-of-mass momentum.
- Introduction of the antiphonon concept through atomic line and ring models.
- Classical analysis of quantum harmonic solid behavior under a Mössbauer-like kick.
Main Results:
- The correspondence principle provides an intuitive classical framework for quantum harmonic solids.
- The concept of the antiphonon is introduced and illustrated.
- Classical analysis successfully predicted and simulation verified the formation of an antiphonon.
Conclusions:
- The Schrödinger Correspondence Principle is a powerful tool for simplifying quantum mechanical problems in harmonic solids.
- The antiphonon concept offers new insights into the dynamics of atomic systems.
- Classical analysis, aided by the correspondence principle, effectively models quantum phenomena like antiphonon formation.
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