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Related Concept Videos

Chirality02:25

Chirality

29.3K
Chirality is a term that describes the lack of mirror symmetry in an object. In other words, chiral objects cannot be superposed on their mirror images. For example, our feet are chiral, as the mirror image of the left foot, the right foot, cannot be superposed on the left foot.
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
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Chirality in Nature02:30

Chirality in Nature

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Chirality is the most intriguing yet essential facet of nature, governing life’s biochemical processes and precision. It can be observed from a snail shell pattern in a macroscopic world to an amino acid, the minutest building block of life. Most of the snails around the world have right-coiled shells because of the intrinsic chirality in their genes. All the amino acids present in the human body exist in an enantiomerically pure state, except for glycine - the sole achiral amino acid.
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Electro-mechanical Systems01:19

Electro-mechanical Systems

1.6K
Electromechanical systems are intricate configurations that effectively combine electrical and mechanical elements to achieve a desired outcome. Central to many of these systems is the DC motor, a device that converts electrical energy into mechanical motion, enabling various applications ranging from simple fans to complex robotic mechanisms.
A key component of the DC motor is the armature, a rotating circuit positioned within a magnetic field. As an electric current passes through the...
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Molecules with Multiple Chiral Centers02:25

Molecules with Multiple Chiral Centers

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Molecules that possess multiple chiral centers can afford a large number of stereoisomers. For instance, while some molecules like 2-butanol have one chiral center, defined as a tetrahedral carbon atom with four different substituents attached, several molecules like butane-2,3-diol have multiple chiral centers. A simple formula to predict the number of stereoisomers possible for a molecule with n chiral centers is 2n. However, there can be a lower number where some of the stereoisomers are...
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Chirality at Nitrogen, Phosphorus, and Sulfur02:30

Chirality at Nitrogen, Phosphorus, and Sulfur

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Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
6.9K
Members Made of Elastoplastic Material01:19

Members Made of Elastoplastic Material

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The behavior of elastoplastic materials under bending stresses, particularly in structural members with rectangular cross-sections, is crucial for predicting material responses and understanding failure modes. Initially, when a bending moment is applied, the stress distribution across the section follows Hooke's Law and is linear and elastic. This distribution means the stress increases from the neutral axis to the maximum at the outer fibers, up to the elastic limit.
As the bending moment...
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A Micropatterning Assay for Measuring Cell Chirality
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Main-Group-Based Electro- and Photoactive Chiral Materials.

Flavia Pop1, Nicolas Zigon1, Narcis Avarvari1

  • 1Laboratoire MOLTECH-Anjou , UMR 6200 CNRS- Université d'Angers , UFR Sciences, Bât. K, 2 Bd. Lavoisier , 49045 Angers Cedex, France.

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Chiral molecules and materials containing main-group elements exhibit unique optical and conducting properties. These advanced materials offer new possibilities in optics and materials science.

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Area of Science:

  • Materials Science
  • Chemistry
  • Physics

Background:

  • Chirality is a fundamental property influencing biological, chemical, and physical processes.
  • Chirality's interaction with light leads to optical effects like the Cotton effect and circularly polarized luminescence, enabling applications in 3D displays and polarized sunglasses.

Purpose of the Study:

  • To review structure-property relationships in chiral molecules, macromolecules, and supramolecules containing main-group elements.
  • To emphasize the impact of chirality on the conducting and optical properties of materials with frontier heteroelements (boron, silicon, phosphorus, sulfur).

Main Methods:

  • This review synthesizes existing research on chiral materials.
  • Focuses on structure-property correlations in main-group element-containing chiral systems.

Main Results:

  • Chirality significantly influences the optical and conducting properties of molecules and materials.
  • Materials incorporating boron, silicon, phosphorus, and sulfur exhibit novel properties.

Conclusions:

  • Chiral materials with main-group elements are poised to revolutionize materials science.
  • Emerging properties include chirality-induced spin-selectivity, circularly polarized luminescence, and electrical magnetochiral anisotropy.