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Published on: May 14, 2019
Formation and Nature of Carbon-Containing Tribofilms
Hongxing Wu1, Arman Mohammad Khan, Blake Johnson
1Key Laboratory of Education Ministry for Modern Design and Rotor Bearing Systems , Xi'an Jiaotong University , Xi'an 710049 , P. R. China.
A novel lubrication approach creates self-healing, wear-protective carbon films from a cyclopropanecarboxylic acid additive. These replenishable hydrocarbon films offer an alternative to traditional coatings like diamond-like carbon (DLC) for reducing friction and wear.
Area of Science:
- Tribology
- Materials Science
- Surface Engineering
Background:
- Minimizing friction and wear is crucial for machine component longevity.
- Diamond-like carbon (DLC) coatings are widely used but have limited wear life.
- Surface pretreatment is often required for effective lubrication and wear protection.
Purpose of the Study:
- To develop a self-generating and replenishable lubrication approach for wear protection.
- To investigate the formation and properties of carbon-containing tribofilms.
- To offer an alternative to conventional DLC coatings with limited wear life.
Main Methods:
- Sliding experiments using a lubricant with cyclopropanecarboxylic acid additive in polyalphaolefin base oil.
- Raman spectroscopy to analyze the composition and structure of formed tribofilms.
- Reactive molecular dynamics simulations to understand tribofilm formation mechanisms.
Main Results:
- Self-generated, wear-protective carbon-containing tribofilms were formed without surface pretreatment.
- Tribofilms exhibited Raman D and G signatures similar to graphite or DLC.
- Experimental and simulation data confirmed tribofilms are high-molecular weight hydrocarbons acting as solid lubricants.
Conclusions:
- A novel lubrication strategy enables the in-situ formation of replenishable, wear-protective carbonaceous tribofilms.
- These self-generated films provide a promising alternative to limited-wear-life coatings.
- The approach enhances tribological performance through high-molecular weight hydrocarbon formation.
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