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Updated: Jan 26, 2026

Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR
Published on: December 16, 2013
Metal(II) Coordination Polymers Derived from Mixed 4-Imidazole Ligands and Carboxylates: Syntheses, Topological
Wei-Dong Li1, Jia-Le Li2, Xing-Zhe Guo3
1School of Chemistry and Chemical Engineering, Fuyang Normal University, Fuyang 236041, China. weidongli2018@163.com.
Abstract:
Four new metal⁻organic coordination polymers [Cu(L)(mpa)]·3H₂O (1), [Co(L)(mpa)]·H₂O (2), [Zn(L)(mpa)]·H₂O (3), and [Cd(L)(mpa)(H₂O)]·H₂O (4) were synthesized by reactions of the corresponding metal(II) salts based on mixed ligands of 1,4-di(1H-imidazol-4-yl)benzene (L) and 4-methylphthalic acid (H₂mpa), respectively. The structures of the complexes were characterized by elemental analysis, FT-IR spectroscopy, and single-crystal X-ray diffraction. Compound 1 exhibits a binodal 4-connected three dimensional (3D) architecture with (6⁵·8)-CdSO₄ topology, while complexes 2 and 3 are isostructural and have two-dimensional (2D) layer structure with (4, 4) sql topology based on the binuclear metal subunits. Complex 4 has the same 2D layer structure with (4, 4) sql topology as complexes 2 and 3, but the inclined interpenetration of parallel sets of layers result in the formation with 2D + 2D → 3D framework. The activated sample 1 shows selective CO₂ uptake over N₂. The photoluminiscent properties together with quantum yield (QY) and luminescence lifetime are also investigated for complexes 3 and 4 in the solid state at room temperature.
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