Ceramic Membranes Photocatalytically Functionalized on the Permeate Side and Their Application to Water Treatment

This work deals with direct coupling of membrane separation and photocatalytic degradation by using photocatalytic ceramic membranes. An unusual configuration is considered here, with the irradiation applied on the permeate side of the membrane in order to mineralize small organic molecules not retained by the membrane. Different types of such membranes are presented. Their functional performance is quantified thanks to a simple experimental method enabling the estimation of the specific degradation rate δ, i.e., the quantity of destroyed organic molecules per unit of time and of membrane surface area. The relevance of δ for the design and scale-up of purification units is then illustrated. Finally, current technological challenges and potential solutions concerning the industrial implementation of such photocatalytic membranes are discussed.