Related Experiment Video
Updated: Jan 23, 2026
Synthesis and Exfoliation of Discotic Zirconium Phosphates to Obtain Colloidal Liquid Crystals
Published on: May 25, 2016
Stability of binary colloidal crystals immersed in a cholesteric liquid crystal
Setarehalsadat Changizrezaei1, Colin Denniston2
1Department of Applied Mathematics, The University of Western Ontario, London, Ontario N6A 5B8, Canada.
Abstract:
In this paper, we model a number of both closed-packed and non-closed-packed crystals inside a cholesteric liquid crystal (LC) with different pitch values and nematic LC through the Landau-de Gennes free-energy method. We used binary boundary conditions (normal and planar anchoring) applied on the surface of colloids as we are interested in investigating the stability of binary crystals. The results indicate that body-centered-cubic (BCC) crystals have a lower-energy lattice defect structure than the diamond crystal, and the most energetically favorable BCC lattice can be formed in a cholesteric liquid crystal with a pitch value commensurate with the lattice spacing. Furthermore, it is shown that a pair of binary colloids can be self-assemble into a stable face-centered-cubic lattice structure inside a nematic LC, as it has the lowest energy comparing to diamond and BCC crystals.
Related Concept Videos
02:42Ionic Crystal Structures
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
01:25Crystal Growth: Principles of Crystallization
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
03:22Colloids
02:46Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
01:26Binary Fission