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Updated: Jan 23, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Hitherto unknown eight-connected frameworks formed from A4B4O12 metal organophosphate heterocubanes
Kamna Sharma1, Sandeep K Gupta1, Aditya Borah1
1Department of Chemistry, IIT Bombay, Powai, Mumbai-400076, India. rmv@chem.iitb.ac.in.
Abstract:
Modulation of a functional group on the distal part of a phosphate ester has been prudently exploited to selectively switch between the formation of D4R SBUs and 3-D framework structures. While amino substitution at the para-position of an aryl phosphate results in the isolation of tetra-amino functionalized discrete D4R zinc phosphate or its 4-connected 3-D framework, the introduction of an acetylamino substituent leads to a single-step assembly of a rare eight-connected 3-D framework solid.
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