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    Area of Science:

    • Materials Science
    • Laser Physics
    • Solid-State Photonics

    Background:

    • Calcium fluoride (CaF2) is a promising host material for solid-state lasers due to its excellent optical properties.
    • Neodymium (Nd3+) doping is widely used to achieve laser emission in various host materials.
    • Fabrication of high-quality fluoride ceramics is crucial for developing advanced laser devices.

    Purpose of the Study:

    • To fabricate Nd,Y:CaF2 and Nd,La:CaF2 ceramics with good optical quality.
    • To investigate the optical and lasing properties of these novel ceramic materials.
    • To demonstrate the first Nd3+-activated CaF2 ceramic laser.

    Main Methods:

    • Ceramic fabrication using reactive sintering and hot isostatic pressing.
    • Optical characterization including transmission spectra, emission spectra, and fluorescence decay measurements.
    • Quasi-continuous-wave laser diode pumping at 791 nm to achieve lasing.

    Main Results:

    • Successfully fabricated Nd,Y:CaF2 and Nd,La:CaF2 ceramics with good optical quality.
    • Observed laser emission at 1064 nm for Nd,Y:CaF2 and 1065 nm for Nd,La:CaF2.
    • Confirmed the feasibility of Nd3+ as a gain medium in CaF2 ceramic lasers.

    Conclusions:

    • Nd3+-activated CaF2 ceramics are viable for laser applications.
    • This work represents the first demonstration of a Nd3+-activated CaF2 ceramic laser.
    • The developed ceramics show potential for future photonic devices.