Doping TiO₂ with CuSO₄ enhances visible light photocatalytic activity for organic pollutant degradation

Photocatalysis is one of the most promising advanced oxidation processes due to the capability of solid catalyst to continuously produce oxidant species under light irradiation. The use of conventional UV lamps is high cost intensive, which undermines the possible implementation in developing countries. Visible light active photocatalysts can overcome these challenges and find a market opportunity for competitive technology implementation. This work proposes the synthesis of visible light active catalyst following a facile sol-gel synthesis that introduces CuSO₄ as dopant in TiO₂. Results present complete abatement of methylene blue in 120 min of treatment under 50 mW cm^-2 of blue light (λ = 450 nm), while commercial P25 TiO₂ presented null abatement under identical conditions. Synthesis parameters including dopant level and calcination temperature allowed defining optimum synthesis conditions based on material characteristics modification and catalytic activity enhancement. A doping level of 0.21 mol% CuSO₄ was identified as optimum condition to enable visible light photocatalysis of doped TiO₂ catalysts calcined at 300 °C. Finally, operational parameters were evaluated defining a wide range of pH operation under 3.0 g L^-1 of catalyst dose to treat up to 20 g L^-1 of highly recalcitrant phenothiazine dye. These optimum conditions allowed complete dye removal under visible light after 120 min of treatment.