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Updated: Jan 22, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Decanuclear Cluster-Based Metal-Organic Framework with a (3,11)-Connected Topology and Highly Sensitive
Jinfang Zhang1,2, Yuhang Liu1, Jiaoyang Feng1
1School of Chemical and Material Engineering , Jiangnan University , Wuxi 214122 , P. R. China.
Abstract:
A 3D heterothiometallic cluster-based metal-organic framework was constructed from the new oligomeric decanuclear heterothiometallic building clusters [W2(μ3-S)6(μ4-S)2Cu8]4+, tetradentate 3-abpt units (3-abpt = 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole), and CN- bridges. It possesses an unprecedented (3,11)-connected architecture, luminescence, and highly sensitive 2,4,6-trinitrophenol (TNP) sensing properties in both organic and aqueous media.
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