Possible Excitonic Insulating Phase in Quantum-Confined Sb Nanoflakes
Zhi Li1,2, Muhammad Nadeem1,2, Zengji Yue1,2
1ARC Centre of Excellence in Future Low-Energy Electronics Technologies (FLEET) , University of Wollongong , Wollongong , New South Wales 2525 , Australia.
Abstract:
In the 1960s, it was proposed that in small indirect band-gap materials, excitons can spontaneously form because the density of carriers is too low to screen the attractive Coulomb interaction between electrons and holes. The result is a novel strongly interacting insulating phase known as an excitonic insulator. Here we employ scanning tunnelling microscopy (STM) and spectroscopy (STS) to show that the enhanced Coulomb interaction in quantum-confined elemental Sb nanoflakes drives the system to the excitonic insulator state. The unique feature of the excitonic insulator, a charge density wave (CDW) without periodic lattice distortion, is directly observed. Furthermore, STS shows a gap induced by the CDW near the Fermi surface. Our observations suggest that the Sb(110) nanoflake is an excitonic insulator.
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