A square antiprism dysprosium single-ion magnet with an energy barrier over 900 K
Sukhen Bala1, Guo-Zhang Huang1, Ze-Yu Ruan1
1Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China. liujliang5@mail.sysu.edu.cn tongml@mail.sysu.edu.cn.
Abstract:
Herein we report a stable and high-performance Dy(iii) single-ion magnet (SIM) showing an energy barrier of 944 K under zero dc field, with an open hysteresis loop up to 6 K. To the best of our knowledge, this is the highest energy barrier for a square antiprism as well as phosphine oxide based Dy-SIMs, reported so far.
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