Trace Gas Detection System Based on All-Optical Quartz-Enhanced Photoacoustic Spectroscopy

An all-optical quartz-enhanced photoacoustic spectroscopy system (QEPAS) with quadrature point stabilization for trace gas detection was reported. The extrinsic interferometry-based optical fiber Fabry-Perot sensor with quadrature point self-stabilization for detection of quartz prong vibration was used to replace the conventional one. The optimal coefficient of the modulation depth was ∼2.2 theoretically and experimentally, corresponding to the modulation depth of ∼0.1795 cm^-1 at an acetylene (C₂H₂) absorption line of 6534.36 cm^-1. Furthermore, the enhancement of QEPAS signal was obtained by using different microresonators. The minimum detectable limit of ∼580 parts per billion by volume (ppbv) was obtained. A normalized noise equivalent absorption coefficient for C₂H₂ of 2.95 × 10^-7 cm^-1·W·Hz^-1/2 was obtained. The detection sensitivity was enhanced by a factor of ∼2.1 in comparison to the conventional QEPAS system. The linear correlation coefficient of the QEPAS signal response to the C₂H₂ concentration was 0.998 within the range from 10 parts per million by volume (ppmv) to 500 ppmv. Finally, the long-term stability of the QEPAS system was evaluated using Allan deviation analysis, and the ultimate detection limit of ∼130 ppbv was reached for an optimum averaging time of ∼108 s at atmospheric pressure and ambient temperature.