Low-cost alkaline substances for the chemical stabilization of cadmium-contaminated soils

Owing to poor waste management in zinc mining, toxic heavy metals, particularly cadmium, are released and contaminate the surrounding agricultural areas. Waterlogging, which is a common practice in rice vegetation, creates anaerobic conditions that result in the conversion of organic matter into acetic acid and the reducing phase. This accelerates the release of cadmium into the water, where it is absorbed into the cells of rice. Chemical stabilization methods can be used to treat cadmium-contaminated soil by reacting an alkaline substance with acetic acid and increasing the soil pH for cadmium immobilization. However, to date, few studies using limestone dust and corncob fly ash have been conducted, and no studies have focused on the neutralization of the produced acetic acid in the anaerobic zone of the soil. This study aims to determine the optimum conditions for cadmium stabilization using different types of low-cost alkaline substances (lime, limestone dust, and corncob fly ash). The effects of alkaline amount, soil moisture content, and reaction time on soil stabilization were investigated. Lime was the most suitable for stabilization among the tested alkaline substances, and increasing the amount of lime can effectively reduce the amount of exchangeable cadmium. At 25% w/w of lime/soil, the exchangeable cadmium can be reduced from 29.3 to 7.8 mg kg^-1. The stabilization efficiencies of limestone dust and corncob fly ash were much lower. The statistical analysis shows that the amount of alkaline substance is the main factor affecting the stabilization performance at a 95% confidence limit for all tested alkalines.