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Updated: Jan 19, 2026
00:26
Hydrogen Bonds in Water
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A three dimensional hydrogen bonded organic framework assembled through antielectrostatic hydrogen bonds
Duncan A Cullen1, Michael G Gardiner1, Nicholas G White1
1Research School of Chemistry, The Australian National University, Canberra, ACT, Australia. nicholas.white@anu.edu.au.
Abstract:
A crystalline 3D hydrogen bonded framework is assembled in water from tetrahedral tetraamidinium cations and antielectrostatically hydrogen bonded bicarbonate dimers. The framework forms in water, and represents a clear demonstration of the potency of these anti-Coulombic hydrogen bonds. Gentle heating of the framework (50 °C) releases CO2 and water to give the neutral tetraamidine compound.
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