Unconventional Route to Oxygen-Vacancy-Enabled Highly Efficient Electron Extraction and Transport in Perovskite Solar...

The ability to effectively transfer photoexcited electrons and holes is an important endeavor toward achieving high-efficiency solar energy conversion. Now, a simple yet robust acid-treatment strategy is used to judiciously create an amorphous TiO₂ buffer layer intimately situated on the anatase TiO₂ surface as an electron-transport layer (ETL) for efficient electron transport. The facile acid treatment is capable of weakening the bonding of zigzag octahedral chains in anatase TiO₂ , thereby shortening staggered octahedron chains to form an amorphous buffer layer on the anatase TiO₂ surface. Such amorphous TiO₂ -coated ETL possesses an increased electron density owing to the presence of oxygen vacancies, leading to efficient electron transfer from perovskite to TiO₂ . Compared to pristine TiO₂ -based devices, the perovskite solar cells (PSCs) with acid-treated TiO₂ ETL exhibit an enhanced short-circuit current and power conversion efficiency.