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Highly sensitive mechano-controlled luminescence in polymer films modified by dynamic CuI-based cross-linkers
Ayumu Karimata1, Pradnya H Patil1, Eugene Khaskin1
1Coordination Chemistry and Catalysis Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa, 904-0495, Japan. juliak@oist.jp.
Abstract:
Dynamic CuI-based mechanophores used as cross-linkers in polybutylacrylates enable highly sensitive detection of mechanical stress even at small strain (<50%) and stress (<0.1 MPa) values via reversible changes in luminescence intensity. Such sensitivity is superior to previously reported systems based on classical organic mechanophores and it allows for direct visualization of mechanical stress by imaging methods.

