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Updated: Jan 1, 2026
A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes
Published on: February 27, 2017
Ultrahigh oxygen-scavenging norbornene copolymers bearing imidazolyl iron complexes for fabricating active and
Yu Wang1, Yui Hasegawa1, Takuma Serikawa1
1Department of Applied Chemistry and Research Institute for Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555, Japan. nishide@waseda.jp oyaizu@waseda.jp.
Abstract:
A tough and transparent norbornene copolymer film affixing an imidazolyl iron-salen complex catalyst exhibited an ultra-high, humidity-independent, and monthly paced oxygen-scavenging capacity up to 300 mL (oxygen gas at STP)/g(film). The homogeneously dispersed and immobilized iron complex in the polymer matrix catalytically contributed to the exceptionally high-yield oxidative consumption of polymer allylic bonds.
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