Synergistically coupling membrane electrochemical reactor with Fenton process to enhance landfill leachate treatment

Landfill leachate is challenging to treat due to its complex composition. Advanced oxidation processes such as Fenton process can be effective to treat leachate. Herein, a previously developed membrane electrochemical reactor (MER) was coupled with Fenton oxidation through providing synergistic benefits with the low solution pH, reduced organics, and ammonia removal/recovery. This two-stage coupled system reduced the leachate COD by 88%, much higher than that from the standalone Fenton process treating raw leachate. In addition, the usage of chemical reagents has been greatly reduced. At a dimensionless oxidant dose of 1.0, the coupled MER-Fenton system reduced the consumption of both FeSO₄⋅7H₂O and H₂O₂ by 39%, H₂SO₄ by 100%, and NaOH by 55%. Consequently, the sludge production was reduced by 51% in weight and 12% in volume. Despite electricity consumption by the MER, the coupled system cost $4.76 per m³ leachate less than the standalone Fenton treatment. More notably, direct Fenton oxidation removed only 21% of ammonia; in comparison the MER-Fenton system removed ammonia by 98% with the possibility for recovery at a rate of 30.6-55.2 kg N m^-3 reactor d^-1. Those results demonstrate that coupling MER with Fenton process could mitigate some inherent drawbacks of Fenton oxidation such as ineffective ammonia removal, high acid and chemical reagents dose requirements, and a large amount of sludge generation. This system may be moved towards practical applications by addressing a few challenges such as using renewable energy to power MER.