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Updated: Dec 26, 2025

Time-resolved Photophysical Characterization of Triplet-harvesting Organic Compounds at an Oxygen-free Environment Using an iCCD Camera
Published on: December 27, 2018
An ultralong room-temperature phosphorescent material based on the combination of small singlet-triplet splitting
Liang Zhang1, Meng Li, Qing-Yu Gao
1College of Chemical Engineering, China University of Mining and Technology, Xuzhou 221116, China. gaoqy@cumt.edu.cn.
Abstract:
Compound AI-N-Cz was conveniently synthesized, and it exhibited ultralong room-temperature phosphorescence (RTP) with a lifetime of 775 ms, which was more than 400 times the RTP lifetime of its isomer AI-Cz (1.9 ms). The ultralong RTP of AI-N-Cz might be due to the combination of small singlet-triplet splitting energy (ΔEST) and H-aggregation, and this could be an efficient strategy for the further design of ultralong organic room-temperature materials.
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