Improved photocatalytic performance of covalent organic frameworks by nanostructure construction
Lifei Liu1, Bingxing Zhang, Xiuniang Tan
1Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. zhangjl@iccas.ac.cn.
Abstract:
Here, we demonstrate for the first time the construction of covalent organic framework (COF) capsules with nanostructured surfaces, which combine advantages of highly accessible surface area, excellent light absorbance, and efficient separation of photogenerated electron-hole pairs. The COF capsules exhibit high activity and selectivity for photocatalytic oxidation under mild conditions.


