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Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

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Electrically Conductive Metal-Organic Frameworks.

Lilia S Xie1, Grigorii Skorupskii1, Mircea Dincă1

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.

Chemical Reviews
|April 11, 2020
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Summary

This review explores strategies for enhancing electrical conductivity in metal-organic frameworks (MOFs). Key approaches include through-bond, extended conjugation, through-space, and guest-promoted pathways for improved charge transport.

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Area of Science:

  • Materials Science
  • Chemistry
  • Nanotechnology

Background:

  • Metal-organic frameworks (MOFs) are porous crystalline materials constructed from metal ions and organic linkers.
  • High electrical conductivity is an uncommon but highly desirable property in MOFs for advanced applications.
  • Current MOF applications are limited by their typically low charge transport capabilities.

Purpose of the Study:

  • To review and analyze strategies for achieving efficient charge transport in metal-organic frameworks.
  • To systematically evaluate different structural approaches that promote electrical conductivity in MOFs.
  • To discuss the benefits, limitations, and future challenges in the development of conductive MOFs.

Main Methods:

  • Analysis of 'through-bond' strategies involving continuous coordination bond chains.
  • Evaluation of 'extended conjugation' approaches creating delocalized electronic systems.
  • Assessment of 'through-space' interactions (e.g., π-π stacking) and 'guest-promoted' conductivity.
  • Review of studies with less defined charge transport pathways.

Main Results:

  • Four primary strategies ('through-bond', 'extended conjugation', 'through-space', 'guest-promoted') have been developed to enhance MOF conductivity.
  • Each strategy offers distinct mechanisms for facilitating charge transport through specific structural features.
  • A systematic overview of relevant MOF structures and their transport properties is presented for each approach.

Conclusions:

  • Significant progress has been made in designing conductive MOFs through various synthetic and structural strategies.
  • Understanding the structure-property relationships is crucial for optimizing charge transport in MOFs.
  • Further research is needed to overcome existing limitations and unlock the full potential of conductive MOFs in electronic applications.