Electroactive magnetic microparticles for the selective elimination of cesium ions in the wastewater

To improve operability as well as the removal efficiency for cesium ions in the wastewater treatment, a novel electrochemically switched ion exchange (ESIX) technique by using electroactive Prussian-blue(PB)-based magnetic microparticles (PB@Fe₃O₄ microparticle) with different uniform particle sizes in the range of 300-900 nm as the adsorption materials was developed. The obtained PB@Fe₃O₄ microparticle were characterized by Scanning electron microscopy (SEM), Transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and Thermogravimetric analysis (TGA). It is found that the PB can be well coated on the surface of Fe₃O₄ microsphere, which can be easily adsorbed on the magnetic electrode substrate for the electrochemical adsorption of Cs⁺ ions. Electrochemical adsorption of 97% Cs⁺ on PB/Fe₃O₄ was achieved in less than 10 min, and the maximum adsorption capacity was 16.13 mg/g, and the distribution coefficient (K_D) of Cs⁺ ions reached as high as 3938. In addition, the electrochemical adsorption behavior of PB@Fe₃O₄ microparticle fitted well with the Freundlich adsorption isotherm and the Pseudo-second-order kinetic models. It is expected that such an ESIX technique using PB@Fe₃O₄ microparticle can be applied for the separation and recovery of dilute Cs⁺ ions from cesium-contaminated solution in a practical process.