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Related Concept Videos

Weak Acid Solutions04:02

Weak Acid Solutions

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Few compounds act as strong acids. A far greater number of compounds behave as weak acids and only partially react with water, leaving a large majority of dissolved molecules in their original form and generating a relatively small amount of hydronium ions. Weak acids are commonly encountered in nature, being the substances partly responsible for the tangy taste of citrus fruits, the stinging sensation of insect bites, and the unpleasant smells associated with body odor. A familiar example of a...
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Electrodeposition01:08

Electrodeposition

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Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
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Extraction: Advanced Methods00:56

Extraction: Advanced Methods

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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Bonding in Metals02:32

Bonding in Metals

51.4K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
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Formation of Complex Ions03:45

Formation of Complex Ions

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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Solid-Solution-Based Metal Alloy Phase for Highly Reversible Lithium Metal Anode.

Song Jin1,2, Yadong Ye1,2, Yijie Niu1,3

  • 1Hefei National Laboratory for Physical Sciences at the Microscale, Hefei 230026, China.

Journal of the American Chemical Society
|April 21, 2020
PubMed
Summary
This summary is machine-generated.

Researchers developed a new lithium metal anode that plates lithium internally into a metal foil. This dendrite-free design enhances cycling stability and safety for high-energy-density batteries.

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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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Area of Science:

  • Electrochemistry
  • Materials Science
  • Energy Storage

Background:

  • Lithium metal batteries offer high energy density but suffer from anode reactivity, dendrite formation, and poor cycling stability.
  • Current strategies to mitigate these issues often fail to prevent surface deposition and associated parasitic reactions.
  • Dendrite growth on lithium metal anodes remains a critical challenge for battery safety and performance.

Purpose of the Study:

  • To demonstrate a novel inward-growth plating mechanism for lithium metal anodes.
  • To overcome the limitations of surface plating and dendrite formation in lithium metal batteries.
  • To improve the cycling stability and safety of high-energy-density energy storage devices.

Main Methods:

  • Utilizing a reversible solid-solution-based alloy phase change to drive lithium plating.
  • Achieving inward-growth plating of lithium atoms into a metal foil (tens of micrometers thick).
  • Investigating the lithiation and delithiation processes involving the solid-solution alloy.

Main Results:

  • Successfully demonstrated dendrite-free lithium plating via inward growth into a metal foil.
  • Achieved an enhanced Coulombic efficiency of 99.5 ± 0.2%.
  • Obtained a high reversible capacity of 1660 mA h g-1 (3.3 mA h cm-2).

Conclusions:

  • The inward-growth plating strategy effectively prevents surface deposition and dendrite formation.
  • This method significantly enhances the cycling stability and safety of lithium metal anodes.
  • The developed anode shows great promise for next-generation high-energy-density batteries.