Desalination behavior analysis of interior-modified carbon nanotubes doped membrane by dielectric spectrum and...

Carbon nanotube (CNT)-doped polyamide (PA) membranes have attracted much attention in reverse osmosis (RO) membranes due to their significant advantages of water flux and desalination. In this study, we synthesized multi-walled carbon nanotube (MWNT)/PA RO membrane by 12-oxodidodecanoic acid methyl ester group interior-modified MWNTs (MWNT-C₁₄H₂₅O₄). Then, their mechanism of desalination behavior was successfully analyzed by combining dielectric relaxation spectrum (DRS) and molecular dynamics (MD) simulation. DRS analysis mainly focuses on two aspects: (1) the water volume fraction, average pore size and dielectric parameters of MWNT-C₁₄H₂₅O₄/PA and PA membranes were obtained by model analysis of DRS data. These data of MWNT-C₁₄H₂₅O₄/PA membrane are higher than PA membrane, which indicates that the water flux of the MWNT-C₁₄H₂₅O₄/PA membrane was higher than that of the PA membrane. (2) Further analysis shows that the MWNT-C₁₄H₂₅O₄/PA membranes have high average charge density, ion solvation barrier and reflection coefficient, which indicates that the added interior-modified MWNT can improve the salt rejection of PA membranes. In the microscopic aspect, the desalination behavior of the MWNT-C₁₄H₂₅O₄/PA and PA membrane was analyzed from the aspects of free volume distribution, the dynamic diffusion process of water and ions. The results show that the microscopic data of dynamic simulation well support the conclusion of the DRS method. This study provides a convenient methodology to characterize the properties of the membrane from the aspect of membrane structure.