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Sample Preparation Using Graphene-Oxide-Derived Nanomaterials for the Extraction of Metals.
Natalia Manousi1, Erwin Rosenberg2, Eleni A Deliyanni3
1Laboratory of Analytical Chemistry, Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece.
Molecules (Basel, Switzerland)
|May 28, 2020
Summary
Graphene oxide nanocomposites effectively extract metal ions for analysis. This review explores their use in analytical chemistry, including modifications with ionic liquids and deep eutectic solvents.
Area of Science:
- Materials Science
- Analytical Chemistry
- Nanotechnology
Background:
- Graphene oxide (GO) possesses a large surface area and excellent stability, enabling diverse applications.
- GO is utilized in analytical chemistry for extracting organic compounds, metal ions, and proteins.
- The negative charge of GO sheets in solution makes them ideal for binding metal ions.
Purpose of the Study:
- This review discusses graphene oxide and its nanocomposites for metal ion extraction.
- It covers applications prior to determination using instrumental analytical techniques.
- The review also explores modifications of GO using ionic liquids and deep eutectic solvents.
Main Methods:
- Review of literature on graphene oxide and its nanocomposites for metal ion extraction.
- Analysis of applications in various sample matrices (biological, environmental, agricultural, food).
- Discussion of functionalization strategies and analytical determination techniques.
Main Results:
- Graphene oxide nanocomposites show significant potential for metal ion extraction and preconcentration.
- Various GO-based materials have been synthesized and evaluated for diverse sample types.
- Functionalization enhances the efficiency and selectivity of metal ion binding.
Conclusions:
- Graphene oxide and its derivatives are highly effective sorbents for metal ion analysis.
- Modification with ionic liquids and deep eutectic solvents offers advanced capabilities.
- These materials are promising for sensitive and selective determination of metal ions.
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