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Core@Satellite Janus Nanomotors with pH-Responsive Multi-phoretic Propulsion
Yi Xing1, Mengyun Zhou1, Tailin Xu1
1Beijing Key Laboratory for Bioengineering and Sensing Technology, Department of Chemistry & Biological Engineering, University of Science & Technology Beijing, Beijing, 100083, China.
Angewandte Chemie (International Ed. in English)
|June 8, 2020
Summary
We developed Janus mesoporous silica-platinum-gold nanomotors that switch propulsion modes in response to pH changes. These nanomotors exhibit multi-phoretic movement for advanced biomedical applications.
Area of Science:
- Nanotechnology
- Materials Science
- Physical Chemistry
Background:
- Janus nanomotors offer tunable propulsion mechanisms.
- Controlling nanomotor behavior in response to stimuli is crucial for applications.
Purpose of the Study:
- To develop novel nanomotors with switchable propulsion modes.
- To investigate pH-responsive multi-phoretic propulsion in core@satellite Janus mesoporous silica-Pt@Au nanomotors (JMPA).
Main Methods:
- Synthesis of core@satellite Janus mesoporous silica-Pt@Au nanomotors.
- Characterization of nanomotor structure and properties.
- Investigation of propulsion mechanisms including self-diffusiophoresis, self-electrophoresis, and self-thermophoresis under varying conditions (H2O2 concentration, pH, laser irradiation).
Main Results:
- JMPA nanomotors demonstrated pH-responsive multi-phoretic propulsion.
- Propulsion mode switched from self-diffusiophoresis to self-electrophoresis upon pH-induced AuNP aggregation.
- Laser irradiation induced self-thermophoresis due to thermal gradients generated by aggregated AuNPs.
Conclusions:
- The JMPA nanomotors exhibit stimuli-responsive switching of propulsion modes.
- This multi-phoretic capability holds significant promise for developing advanced nanomachines in biomedical fields.
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