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Updated: Dec 12, 2025

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
Published on: January 30, 2015
Spin crossover modulation in a coordination polymer with the redox-active bis-pyridyltetrathiafulvalene (py2TTF)
Lisa Zappe1, Sophie Schönfeld, Gerald Hörner
1Department of Chemistry, University of Bayreuth, Universitätsstraße 30, 95448 Bayreuth, Germany. weber@uni-bayreuth.de.
Abstract:
A one-dimensional FeII coordination polymer (CP) has been formed which includes the redox-active ligand bis-pyridyltetrathiafulvalene (py2TTF) and a Schiff base-like N2O2 ligand. This CP is both spin crossover (SCO) and redox-active in the solid-state, and chemical oxidation results in SCO modification.
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