In-situ Raman spectroscopic measurements of the deformation region in indented glasses

This paper describes the design and integration of a custom-built optical instrument for in-situ Raman microscopy suitable for collecting high-quality spectroscopic data during the indentation of glass materials. It will further show that the reported experimental setup enables meaningful in-situ spectroscopic observations during indentation of fused silica at forces in the millinewton range. The aim of the paper is to demonstrate the vital importance of matching the analysis volume of the Raman microscope with the indentation-induced deformation volume to capture the full extent of the related spectral alterations by minimizing spectral contributions from the unperturbed bulk material (in-situ and ex-situ) and indenter probe (in-situ only). In this context, the paper will also touch upon possible pitfalls in ex-situ and in-situ Raman measurements on indented glasses in cases where the analysis and deformation volumes are not well matched and describe the misinterpretations that may result.