A mass-producible integrative structure Pt alloy oxygen reduction catalyst synthesized with atomically dispersive...

Oxygen reduction reaction (ORR) catalyst is one of the most significant influential factors for the application of proton exchange membrane fuel cells. This work introduces a mass-producible high-performance PtZn alloy integrative structure ORR catalyst, synthesized with the atomically dispersive metal-organic framework precursors. This PtZn catalyst displays excellent catalytic activity with the onset reduction potential of 1.0 V_RHE@ 0.16 mA cm^-2 (Reversible hydrogen electrode; RHE) and the half-wave potential of 0.934 V_RHE for the ORR catalysis. The calculated specific activity and mass activity at 0.9 V are 9.44 A m^-2 and 544 A g_Pt^-1, respectively, which are 5.62 times and 5.77 times as high as the commercial Pt/C. The mass activity is remarkably higher than the target put forward by the Department of Energy (DOE; 440 A g_Pt^-1). Furthermore, this PtZn catalyst also exhibits outstanding stability after the 10,000 potential cyclic degeneration test. The ORR current is much higher than Pt/C in the whole potential range not only before but also after the 10,000 potential cycles with identical Pt loading. This catalyst has a multifarious active-site catalytic structure with PtZn alloyed particles and atomically dispersive metal-N active sites on the N-doped graphited carbon matrix, exhibiting appealing ORR catalytic activity and sound stability for the application and scalable production of fuel cell catalysts.