Incorporating Indium Selenide Nanosheets into a Polymer/Small Molecule Binary Blend Active Layer Enhances the...

In this report, we demonstrated that the incorporation of 15 wt % two-dimensional transition-metal dichalcogenide materials indium selenide (In₂Se₃) nanosheets into a polymer (PM6)/small molecule (Y6) active layer not only increased its light absorption but also enhanced the long-term stability of the PM6/Y6/In₂Se₃ ternary blend organic photovoltaic (OPV) devices. The power conversion efficiency (PCE) of the device was improved from 15.7 to 16.5% for the corresponding PM6/Y6 binary blend device. Moreover, the PM6/Y6/In₂Se₃ device retained 80% of its initial PCE after thermal treatment at 100 °C for 600 h; in comparison, the binary blend device retained only 62% of its initial value. This relative enhancement of 29% resulted from the In₂Se₃ nanosheets retarding or facilitating molecule packing in different orientations that stabilizes the morphology of the active layer. We adopted a modified kinetics model to account for the intrinsic degradation of the OPV; the degradation-facilitated energy for the degradation kinetics of the PCE for the ternary blend device was 5.3 kJ/mol, half of that (11.3 kJ/mol) of the binary blend device, indicating a slower degradation rate occurring for the case of incorporating In₂Se₃ nanosheets. Therefore, the incorporation of transition metal dichalcogenide nanosheets having tunable band gaps and large asymmetric shape appears to be a new way to improve the long-term stability of devices and realize the practical use of OPVs.