Electrochemical Synthesis of Large Area Two-Dimensional Metal-Organic Framework Films on Copper Anodes

Owing to their excellent physical and electrical properties, metal-organic framework (MOF) materials with well-defined supramolecular structures have received extensive research attention. However, the fabrication of large-area two-dimensional (2D) MOF films is still a significant challenge. Herein, we propose a novel electrochemical (EC) synthesis method for the preparation of large-area Cu₃ (HHTP)₂ MOF film on single-crystal Cu (100) anode. The surface reaction was achieved via charge-induced molecular assembly. The synthesized MOF film exhibited a high crystalline quality with an electrical conductivity of approximately 0.087 S cm^-1 , which was around 1000 times larger than the previously reported values for the same material prepared by the interface method. In addition, Cu₂ (MTCP), Cu₃ (BTPA)₂ , and Cu₃ (TPTC)₂ MOF films were synthesized on Cu foil with the same strategy, which confirmed the universality of the proposed method. This controllable EC method can be effectively applied to the industrial-scale production of 2D MOF films on Cu foil.