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Area of Science:

  • Condensed Matter Physics
  • X-ray Science
  • Materials Science

Background:

  • Time-resolved resonant inelastic X-ray scattering (RIXS) is an emerging technique.
  • X-ray free electron lasers (FELs) enable advanced X-ray measurements.
  • FEL jitter is an inherent challenge in self-amplified spontaneous emission.

Purpose of the Study:

  • To evaluate the impact of FEL jitter on time-resolved RIXS measurements.
  • To assess the performance of a microchannel plate (MCP) based Timepix detector for RIXS.
  • To investigate RIXS at the Ti L3-edge on TiSe2.

Main Methods:

  • Utilized a microchannel plate (MCP) based Timepix soft X-ray detector.
  • Conducted time-resolved RIXS measurements at the Ti L3-edge.
  • Performed pulse-by-pulse data acquisition and analysis.

Main Results:

  • Less than 2% of X-ray FEL pulses yielded usable signals.
  • FEL jitter, low spectrometer efficiency, and low RIXS quantum yield limited data statistics.
  • Achieving sufficient data statistics while maintaining temporal and energy resolution was challenging.

Conclusions:

  • Current X-ray FEL limitations hinder time-resolved RIXS data acquisition.
  • Future MHz-class X-ray FELs (e.g., European XFEL, LCLS-II) are needed.
  • Advanced detectors, like the Timepix prototype, are essential for RIXS improvements.