Calorimetric Studies of Magnesium-Rich Mg-Pd Alloys

Solution calorimetry with liquid aluminum as the bath was conducted to measure the enthalpy of a solution of magnesium and palladium as well as the standard formation enthalpies of selected magnesium-palladium alloys. These alloys were synthesized from pure elements, which were melted in a resistance furnace that was placed in a glove box containing high-purity argon and a very low concentration of impurities, such as oxygen and water vapor. A Setaram MHTC 96 Line evo drop calorimeter was used to determine the energetic effects of the solution. The enthalpies of the Mg and Pd solutions in liquid aluminum were measured at 1033 K, and they equaled -8.6 ± 1.1 and -186.8 ± 1.1 kJ/mol, respectively. The values of the standard formation enthalpy of the investigated alloys with concentrations close to the Mg₆Pd, ε, Mg₅Pd₂, and Mg₂Pd intermetallic phases were determined as follows: -28.0 ± 1.2 kJ/mol of atoms, -32.6 ± 1.6 kJ/mol of atoms, -46.8 ± 1.4 kJ/mol of atoms, and -56.0 ± 1.6 kJ/mol of atoms, respectively. The latter data were compared with existing experimental and theoretical data from the literature along with data calculated using the Miedema model.