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Updated: Nov 15, 2025

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Fused Filament Fabrication-4D-Printed Shape Memory Polymers: A Review.

Sara Valvez1, Paulo N B Reis1, Luca Susmel2

  • 1C-MAST, Department of Electromechanical Engineering, University of Beira Interior, Calçada Fonte do Lameiro, 6201-100 Covilhã, Portugal.

Polymers
|March 3, 2021
PubMed
Summary

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This review examines the mechanical properties of 4D printing using fused filament fabrication (FFF). It highlights shape memory polymer compounds (SMPCs) as promising materials for stimuli-responsive 4D-FFF components.

Area of Science:

  • Materials Science
  • Mechanical Engineering
  • Additive Manufacturing

Background:

  • Additive manufacturing (AM) builds objects layer-by-layer.
  • 4D printing integrates time with 3D printing, creating components that change shape or properties in response to stimuli.
  • Shape memory polymers (SMPs) and their compounds (SMPCs) are key materials for 4D printing due to their shape memory effect (SME).

Purpose of the Study:

  • To critically review existing research on the mechanical properties of 4D printing materials fabricated using fused filament fabrication (FFF).
  • To provide an updated overview of the state-of-the-art in 4D-FFF technology.
  • To assess the potential of 4D-FFF for engineering applications, focusing on structural integrity.

Main Methods:

  • Literature review of studies focusing on the mechanical properties of 4D-FFF materials.
Keywords:
4D printingadditive manufacturing (AM)fused filament fabrication (FFF)mechanical performanceshape memory effect (SME)structural integrity

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  • Analysis of shape memory materials, particularly shape memory polymer compounds (SMPCs).
  • Focus on fused filament fabrication (FFF) as the primary AM technique.
  • Main Results:

    • Shape memory polymer compounds (SMPCs) offer an effective alternative to traditional SMPs for 4D printing applications.
    • Fused filament fabrication (FFF) is a widely adopted AM technique suitable for 4D printing.
    • The mechanical properties of 4D-FFF materials are crucial for their structural integrity and application potential.

    Conclusions:

    • 4D-FFF printing demonstrates significant potential for various engineering applications.
    • Further research into the mechanical properties of 4D-FFF materials is essential for optimizing structural integrity.
    • SMPCs are a key material class for advancing 4D printing technologies.