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Author Spotlight: Characterizing Porous Materials for Aiding the Development of Robust Metal-Organic Frameworks with Adsorption Behavior
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Characterization of Nanoporous Materials.

M Thommes1, C Schlumberger1

  • 1Institute of Separation Science and Technology, Friedrich-Alexander-Universität Erlangen-Nürnberg, Erlangen 91058, Germany;

Annual Review of Chemical and Biomolecular Engineering
|March 26, 2021
PubMed
Summary

Understanding nanoporous materials

Area of Science:

  • Materials Science and Chemistry

Background:

  • Nanoporous materials with tailored pore structures are crucial for gas storage, separation, and catalysis.
  • Advances in material design, including hierarchical pore systems, enhance application potential.

Purpose of the Study:

  • To detail methods for analyzing textural properties of nanoporous materials.
  • To correlate these properties with performance in gas storage, separation, and catalysis.

Main Methods:

  • Advanced physisorption characterization using high-resolution experimental protocols.
  • Statistical mechanics-based methods, including density functional theory and molecular simulation.
  • Mercury porosimetry for macro-pore analysis and complementary liquid-phase techniques.

Main Results:

Keywords:
density functional theorymercury porosimetrynanoporesphysical adsorptionpore condensationtextural characterization

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  • Reliable analysis of pore size, volume, and network connectivity is achievable.
  • Understanding adsorption and phase behavior of confined fluids is enhanced.
  • Recent advances in mercury intrusion/extrusion mechanisms are discussed.

    • Conclusions:

    • Accurate characterization of nanoporous materials is key to optimizing their performance.
    • Integrated approaches combining adsorption, mercury porosimetry, and other techniques provide comprehensive insights.
    • Further development of characterization methods will drive innovation in nanoporous material applications.