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EDTA titrations may necessitate masking and demasking agents to temporarily protect a particular metal ion in a mixture from the EDTA reaction. These agents facilitate the sequential analysis of the metal ions by forming stable complexes with some—but not all—metal ions during certain steps.
There are many masking agents, such as cyanide, fluoride, triethanolamine, thiourea, and 2,3-bis(sulfanyl)propan-1-ol (formerly 2,3-dimercapto-1-propanol), with the masking agent chosen based on...
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Refined extreme ultraviolet mask stack model.

I A Makhotkin, M Wu, V Soltwisch

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    This summary is machine-generated.

    A new extreme ultraviolet (EUV) mask model improves photo-lithography simulations by combining EUV and X-ray reflectivity data for higher accuracy. This refined model enhances performance predictions for high-numerical aperture EUV lithography (EUVL) imaging.

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    Area of Science:

    • Materials Science
    • Optical Engineering
    • Semiconductor Manufacturing

    Background:

    • Accurate modeling of extreme ultraviolet (EUV) mask stacks is crucial for advanced photo-lithography.
    • Existing models may not fully capture the complex optical properties of multilayer and absorber layers.
    • High-numerical aperture (high-NA) EUV lithography (EUVL) demands precise simulation tools.

    Purpose of the Study:

    • To develop a refined model of an EUV mask stack for accurate performance simulations in high-NA EUVL.
    • To improve the description of optical constants and layer interfaces within the mask stack.
    • To create both high-resolution and computationally efficient low-resolution models for simulation.

    Main Methods:

    • Combined analysis of measured EUV and X-ray reflectivity of a mask blank.
    • Utilized a "free-form analysis" procedure to determine optical constant depth profiles and layer interface shapes experimentally.
    • Developed a high-resolution model (sublayers as thin as 0.25 nm) and derived a low-resolution model (sublayers > 2 nm) for simulation efficiency.

    Main Results:

    • The refined model provides a more accurate description of reflectivity compared to models based solely on EUV reflectivity.
    • The free-form analysis yielded high-resolution optical constant depth profiles.
    • A low-resolution model was successfully derived from the high-resolution model for reduced simulation effort.

    Conclusions:

    • The developed EUV mask model accurately represents industry-standard mask blanks.
    • The model facilitates more reliable performance simulations for high-NA EUVL.
    • This work advances the accuracy and efficiency of EUV lithography modeling.