Hydroplastic Micromolding of 2D Sheets

Processing 2D sheets into desired structures with high precision is of great importance for fabrication and application of their assemblies. Solution processing of 2D sheets from dilute dispersions is a commonly used method but offers limited control over feature size precision owing to the extreme volume shrinkage. Plastic processing from the solid state is therefore a preferable approach to achieve high precision. However, plastic processing is intrinsically hampered by strong interlayer interactions of the 2D sheet solids. Here, a hydroplastic molding method to shape layered solids of 2D sheets with micrometer-scale precision under ambient conditions is reported. The dried 2D layered solids are plasticized by intercalated solvents, affording plastic near-solid compounds that enable local plastic deformation. Such an intercalated solvent-induced hydroplasticity is found in a broad family of 2D materials, for example graphene, MoS₂ , and MXene. The hydroplastic molding enables fabrication of complex spatial structures (knurling, origami) and microimprinted tubular structures down to diameters of 390 nm with good fidelity. The method enhances the structural accuracy and enriches the structural diversity of 2D macroassemblies, thus providing a feasible strategy to tune their electrical, optical, and other functional properties.