Sorption of Se(IV) from aqueous solution by wheat bran-hydroxyapatite (HA) composite

Natural biocompatible material is promising candidate for selenite sorption from water since it allows to reuse selenium while dispose of waste materials. In this study, innovative wheat bran-hydroxyapatite (HA) composite was prepared by in situ precipitation method. Scanning electronic microscopy (SEM) and X-ray diffraction (XRD) revealed that the hydroxyapatite aggregated in the fiber matrix of the wheat bran. The results of batch sorption experiments including sorption kinetics, isotherms, and the effect of solution pH showed that the sorption of Se(IV) on the wheat bran-HA adsorbent was fast, endothermic, and pH-independent in the range from 5.0 to 7.0. Fourier transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis suggested that interaction occurred between Se(IV) and the hydroxyl groups on the composite. Column studies showed that wheat bran-HA composite was suitable to be utilized for continuous Se(IV) removal. The wheat bran-HA composite has a potential application for Se(IV) removal in water treatment.