Conjugated Cationic Pp-x Formed on g-C₃N₄ for Photocatalyzed Water Splitting

Polycationic Pp-x@g-C₃N₄ composite was synthesized through an in situ polymerization process of N-alkylpyridinium acetylenic alcohol bromide (p-x) above the surface of g-C₃N₄. The structure of p-0 and the Pp-x@g-C₃N₄ properties were checked by modern technologies. Photocatalytic tests of Pp-x@g-C₃N₄ in water splitting unveiled much better Pp-x@g-C₃N₄ hydrogen evolution activities by comparison with both g-C₃N₄ and Pp-0. The hydrogen production by Pp-0@g-C₃N₄ was 1654.5 μmol h^-1 g^-1, which is ∼26- and 22-fold greater in relation to what g-C₃N₄ and Pp-0 produced (62.7 and 75.0 μmol h^-1 g^-1, respectively), suggesting strong bilateral and synergistic interactions of g-C₃N₄ with Pp-0. Although the lengthening methylene chain in the polymers weakened the hydrogen generation ability of Pp-x@g-C₃N₄, the conjugated double bonds, solubilization, and dispersion of Pp-x polycationic surfactants made Pp-x@g-C₃N₄ superior to g-C₃N₄ in water splitting. Due to the readily available raw materials, a simple way of preparation (starting chemicals to p-0 to Pp-0@g-C₃N₄), high photocatalysis efficiency, light irritation stability, recyclable ability, and low toxicity, Pp-0@g-C₃N₄ is a good candidate for water splitting.