Coumarin based thiosemicarbazones as effective chemosensors for fluoride ion detection

Anion sensing have attained immense importance as these charged ions are prevailing in agriculture industry and in heavy industry and therefore in the environment around us, chemosensors are commencing to claim several applications as their role is being better perceived day by day. In the current study, coumarin based thiosemicarbazone R-1 (phenyl moiety) and R-2 (benzyl moiety) were synthesized. It was observed that there were variations in the sensing patterns of compound bearing benzyl group, as compared to the simple phenyl group bearing receptor. Different techniques were used to confirm the interaction of coumarin based receptors with anions. These techniques included naked-eye test, UV-visible, 1H NMR, and fluorescence spectroscopic techniques. The synthesized receptors showed selectivity for fluoride ions. Benesi-Hildebrand equation was employed for determining the detection limits and binding constants values. The synthesized receptors were employed as efficient chemosensors in real life samples and satisfactory results were obtained.