Characterization and risk assessment of polycyclic aromatic hydrocarbon emissions by coal fire in northern China

Coal spontaneous combustion is known to emit a variety of organic carcinogenic pollutants, polycyclic aromatic hydrocarbons (PAHs) are the most prominent. The Wuda coalfield is a coal fire-prone region in northern China. Coal fire sponges (CFS), a sponge-like contaminated soil protrusion, occur widely in the Suhaitu mining area. PAHs concentrations in CFS were measured via GC × GC-TOFMS. The average total PAHs concentration in the central annulus (A) was 17,416 μg kg^-1 and ranged from 292 to 218,251 μg kg^-1. Moreover, the study exhibited a heavily contaminated level (1000 μg kg^-1). Low molecular weight PAHs were dominant, accounting for more than 50% of the total PAHs. Among them, naphthalene (Nap) and phenanthrene (Phe) were the most prominent, and the correlation between Phe and Nap + Phe was highly significant (R² > 0.9). Our findings indicated that Nap and Phe contents may constitute a novel indicator to identify coal fire emission sources. Cancer risk calculations indicated that all annulus is already at a potential risk stage (10^-6-10^-4) for child or adults. CFS is not only a coal fire-associated PAH sink but also an atmospheric PAH emission source and, therefore, warrants the attention of local authorities.