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Exfoliation and Analysis of Large-area, Air-Sensitive Two-Dimensional Materials
Published on: January 5, 2019
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Two-Dimensional Black Phosphorus: An Emerging Anode Material for Lithium-Ion Batteries
JiPing Zhu1, GuangShun Xiao2, XiuXiu Zuo2
1School of Materials Science and Engineering, Hefei University of Technology, Hefei, 230009, People's Republic of China. jpzhu@hfut.edu.cn.
Nano-Micro Letters
|June 17, 2021
Summary
Two-dimensional black phosphorus (2D BP) shows promise for lithium-ion batteries but faces challenges in synthesis, stability, and volume expansion. This review covers preparation, properties, and applications of 2D BP as an anode material.
Area of Science:
- Materials Science
- Electrochemistry
- Nanotechnology
Background:
- Two-dimensional black phosphorus (2D BP) is an emerging material with unique properties.
- Its tunable bandgap, electrochemical, mechanical, thermodynamic, and photoelectric properties offer significant research value.
- 2D BP has advanced electrochemical energy storage, particularly lithium-ion batteries.
Purpose of the Study:
- To systematically review the preparation methods of phosphorene.
- To discuss the structure, properties, environmental instability, and passivation techniques of 2D BP.
- To analyze the application and challenges of 2D BP as an anode material for lithium-ion batteries.
Main Methods:
- Literature review of recent research on 2D BP in energy storage.
- Comparison of different phosphorene preparation techniques.
- Analysis of 2D BP's properties, stability, and passivation strategies.
Main Results:
- 2D BP offers excellent potential for lithium-ion batteries due to its properties.
- Key challenges include large-scale synthesis, environmental stability, and volume expansion.
- Passivation techniques are crucial for addressing instability.
Conclusions:
- 2D BP is a promising anode material for next-generation lithium-ion batteries.
- Overcoming synthesis and stability issues is critical for practical application.
- Future research should focus on scalable production and enhanced durability.

